This case history investigates equipment failure in a glycol unit. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Their mixed microstructure provides improved resistance to chloride stress corrosion cracking in comparison to austenitic stainless steel types 304 and 316. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. This is a phenomenon of degradation of a material due to the combined action of corrosion and applying a constant lo. Heat treatment for improved stresscorrosion resistance of 177 ph stainless steel by carl r. Localized corrosion can accelerate the corrosion failure of steel pipelines and endanger their longterm service security. Corrosion is related to the susceptibility of the material to the environment, while stresses may be residual, external.
What causes stress corrosion cracking in pipelines. As 304 with addition of niobium and or tantalum to prevent carbide precipitation during welding. Stress corrosion cracking facts and how to reduce the. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed. Stress corrosion cracking an overview sciencedirect topics. Stainless steel is known for its corrosion resistance in many environments in which carbon and low alloy tool steels would corrode. Stress corrosion cracking on an insulated austenitic. Coating for 3xx stainless steel to prevent stress corrosion cracking. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Elements of corrosion damaging stainless steel stainless. Stress corrosion cracking of carbon steel in carbonate. To prevent water and chlorides from reaching the stainless steel, the external barrier must be designed properly and maintained periodically. Postweld heat treatment to avoid stress corrosion cracking. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Stress corrosion cracking scc is a type of environmentallyassisted cracking eac, or the formation of cracks caused by various factors combined with the environment surrounding the pipeline. Why are austenitic stainless steels more susceptible to.
Inhibitors may be effective at controlling scc, although the requirements are rather different from those for the inhibition of general corrosion. Avoid stress corrosion cracking of stainless steel this case history investigates equipment failure in a glycol unit jain, a. Postweld heat treatment to avoid stress corrosion cracking twi. Postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. Austenitic and stainless steels, chlorides, higher strength, higher chloride, higher. Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. This type of decomposition can break down the mechanical properties of steel in days rather than months or years.
Wet hydrogen sulfide h2s cracking inspectioneering. Avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments synopsis this maintenance best practice guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic containing fluids. By stress corrosion cracking, usually the ductile metals and alloys show brittle failure by the combined action of tensile stress and some specific corrosion environment. Avoiding iron pickup and maintaining product purity. This oxide layer is referred to as a passive layer since it renders the surface. Stainless steels rustresistant properties make it an ideal material for many applications including building materials that enhance modern aesthetic appeal. Stress corrosion cracking scc is a common issue with many specialty alloys. Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will. In hydrocarbon processing industry hpi facilities, austenitic stainless steel ss is used for several reasons, including. To print this bulletin on stress corrosion cracking, please click here stress corrosion cracking scc happens at the intersection of a susceptible material, working or residual stress experienced above the scc threshold, and a corrosive environment.
Helloi am looking for a coating for 3 series stainless steel that will prevent the corrosion that can lead to stress corrosion cracking. In this chapter, the conditions for the occurrence of scc are first introduced. Stress corrosion cracking in a brewery paul mueller company. Stresscorrosion cracking scc is a cracking process that requires the simultaneous action. Rare, yet severe, stress corrosion cracking is the result of tensile stress combined with elevated temperature, and moisture. As the name implies, localized corrosion affects only specific local areas rather than the broad surface of the metal. Stress corrosion cracking of insulating jackets often results from airborne salts in coastal regions. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially. Stress corrosion cracking happens at the intersection of a susceptible material. A general definition of the phenomenon is that scc is the fracture of a material by the simultaneous action of a tensile stress and a corrosive environment. Scc and fundamental mechanistic understanding of stainless steels.
The blistering damage tends to form parallel to the. Stress corrosion cracking is the cracking of a susceptible metal under the mixed. To avoid the risk of stress corrosion cracking, lower strength alloys may be. For example, chloride stress corrosion cracking of austenitic stainless steels has. Stress corrosion cracking scc of duplex stainless steel. Alternatively, a specialized coating can be applied to the steel to prevent direct contact with chlorides in the environment. However, as mentioned earlier, it isnt just the impact of environmental corrosion on a material but the combination of environmental corrosion and the application of a tensile stress above critical values that leads to scc. The trapped solution environment usually causes additional serious corrosion damages to the pipeline steel and might promote localized corrosion, such as pitting, crevice corrosion, and stress corrosion cracking scc. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Stress corrosion cracking of carbon steel in ethanol.
Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. Paper presented at stainless steel world 2005 conference, maastricht, the netherlands, 810 november 2005. To avoid the risk of stress corrosion cracking, lower strength alloys may be substituted for higher strength alloys. The risk of stress corrosion cracking in certain alloys of this category can be avoided by following rigidly the recommended solution heat treatment temperature and followed by slow quenching. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Corrosionpedia what is stress corrosion cracking scc. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Hardenable stainless steels, like other highstrength steels, are susceptible to cracking under the combined influence of tensile stress and corrosion, depending on the severity of the stress, the nature of the media and to a large extent, on their hardness. Chloride stress corrosion cracking in austenitic stainless steel. Local chemistryelectrochemistry and stress corrosion.
From observations of the characteristics of nitrate and hydroxide solutions, known to promote stress corrosion cracking scc in carbon steels, and from the form of potentiodynamic polarization curves and the structural dependence of the corrosive attack, it was predicted that carbonate solutions would also produce intergranular stress corrosion in carbon steels. Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage. Stress corrosion cracking scc is one failure mode that may occurred on hot insulated austenitic stainless steel pressure vessels and piping. Scc occurs as a result of a combination between corrosion and tensile stress. Different kinds of corrosion on stainless steel montanstahl. Why are austenitic stainless steels more susceptible to chloride stress corrosion cracking than ferritic stainless steels. With stainless steel it takes the form of pitting, crevice corrosion and stress corrosion cracking scc. Austenitic 300 series stainless steels ss have a significant sensitivity. When steam tracing is used within insulation, extra precautions are needed to resist stress cracking corrosion.
Solutions containing less than 1 ppm are normally considered safe. Stress corrosion cracking of hardenable stainless steels. Avoid stress corrosion cracking of stainless steel. Corrosion of unprotected carbon steel occurs even inside reinforced. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. A discussion started in 1996 and continuing through 1998. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. The probability of failure and the speed of crack propagation are governed by the temperature of the stainless steel and the chloride concentration at the metal surface. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. There are, consequently, a number of approaches that we can use to prevent. The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Jun 09, 2014 avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments synopsis this maintenance best practice guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic containing fluids. Polythionic acid stress corrosion cracking deterioration.
Pdf stress corrosion cracking of stainless steel components in. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. This mode of attack is termed stress corrosion cracking scc. Is there anything you can do to 316 stainless steel to make it acceptable for use in a chloride environment, or is it just recomended to avoid 316 stainless steel in. Preventing stress corrosion cracking of austenitic stainless steels in. Stress corrosion cracking scc of austenitic stainless. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. The aerospace industry started with higher strength alloys in 1950s, such as 7079t651, which showed a poor resistance to stress corrosion cracking. Stress corrosion cracking scc is defined as the growth of cracks due to the. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Thats why we need to avoid stress corrosion cracking.
Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stress corrosion cracking scc of austenitic stainless steel weld metal. Stress corrosion cracking international institute of. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. This, along with the smoothed surface conditions and lack of surface hydrogen, will considerably reduce the. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. Chloride stress corrosion cracking in austenitic stainless. Chloride stress corrosion cracking and 316 stainless steel. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. To avoid pitting corrosion, its important to use a grade of stainless steel that is specifically resistant to chloridessuch as grade 316 stainless steel. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools.
At a highly increased rate, it is unlike that of other varieties. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel. Austenitic steel is sensitive to this type of corrosion above 60c in the presence of dissolved oxygen. Grimsley goddard space flight center 1 introduction the advent of rocket propulsion, with a concomitant increase in the requirements of service life and reliability, has given a new importance to the compatibility of metallic parts with liquid. Is there anything you can do to 316 stainless steel to make it acceptable for use in a chloride environment, or is it just recomended to avoid 316 stainless steel in this application. Avoiding stress corrosion cracking of carbon low alloy and. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. Under controlled laboratory testing, the introduction of the electropolishing process, increases the corrosion resistance of these austenitic grades of stainless steel by up to 30 times. Heat treatment for improved stresscorrosion resistance of.
Duplex stainless steels have high resistance to localized corrosion particularly pitting, crevice corrosion, and stress corrosion cracking. Because stainless steel is a poor conductor of heat, it is often used as a thin surface cladding over a core of copper or aluminium, which conduct heat more readily. Stainless steel gains its ability to resist corrosion by forming a. This cracking can also occur when ammonia is intentionally added to process streams as a neutralizer by someone unaware of its potential effect on brass tubes. Stress corrosion cracking international institute of marine. The corrosion resistance is a result of a very thin about 5 nanometers oxide layer on the steels surface. Controlling stress corrosion cracking corrosion doctors. Stress corrosion cracking scc can slowly destroy your brewery equipment without warning. Stainless steels are more resistant to general corrosion compared with carbon steel. Here, i just want to show some important features in stress corrosion cracking.
Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Scc in a 316 stainless steel chemical processing piping system. In 2007, badak lng experienced this problem on its amine regenerator pressure vessel where the shell are insulated and made of austenitic stainless steel. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. Duplex grades are usually divided into three subgroups based on their corrosion resistance. Environmental cracking is a broad term that includes corrosion fatigue, hightemperature hydrogen attack, hydrogen blistering, hydrogen embrittlement, liquid metal embrittlement, season cracking, caustic embrittlement, stress corrosion cracking, stepwise cracking, sulfide corrosion cracking and sulfide stress cracking. I have been reading into stress corrosion cracking scc caused by chlorides, which i understand can be quite an issue. Corrosion of stainless steels stainless steels coursera. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. What is the maximum chloride in ppm that can be allowed in. These were changed to alloys with lower stress levels. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination.